Chemical Bonding and Molecular StructureMind Map

Ionic and covalent bonding are the two basic ways atoms combine. Ionic bonding involves transfer of electrons from an electropositive atom to an electronegative atom, producing oppositely charged ions held by electrostatic attraction. It is favored by low ionization enthalpy, high electron gain enthalpy and high lattice enthalpy. Covalent bonding involves sharing of electron pairs between atoms, usually non-metals, to attain stable valence-shell arrangements. Lewis dot structures show valence electrons, bonding pairs and lone pairs. The octet rule is useful but has exceptions such as BF3, PCl5, SF6 and NO. Formal charge helps choose the best Lewis structure, while resonance explains delocalization when one structure is insufficient. Polar covalent bonds arise due to unequal sharing of electrons.

Bond parameters are measurable quantities that describe the nature, strength and geometry of chemical bonds. Bond length is the equilibrium distance between two bonded nuclei and generally decreases as bond order increases. Bond angle is the angle between two bonds around a central atom and is strongly influenced by hybridization and lone-pair repulsion. Bond enthalpy measures the energy required to break a bond in the gaseous state and indicates bond strength. Bond order represents the number of bonds between atoms or, in molecular orbital theory, half the difference between bonding and antibonding electrons. Dipole moment measures polarity and depends on both bond polarity and molecular shape. NEET often asks trend comparisons using these parameters.

VSEPR theory, or Valence Shell Electron Pair Repulsion theory, predicts molecular shapes by assuming that electron pairs around a central atom repel each other and arrange as far apart as possible. Both bonding pairs and lone pairs are counted as electron domains, but molecular shape is described using only the positions of atoms. The strength of repulsion follows lone pair-lone pair greater than lone pair-bond pair greater than bond pair-bond pair. Therefore, lone pairs compress bond angles and distort ideal geometries. Two electron domains give linear geometry, three give trigonal planar, four give tetrahedral, five give trigonal bipyramidal and six give octahedral electron-pair geometry. NEET strongly focuses on shapes of BeCl2, BF3, CH4, NH3, H2O, PCl5, SF6, XeF2 and XeF4.

Valence bond theory explains covalent bond formation by overlap of half-filled atomic orbitals. Greater overlap gives stronger bonds, and the bond lies in the region where electron density is concentrated between nuclei. End-to-end overlap forms a sigma bond, while sidewise overlap forms a pi bond. Hybridization is the mixing of atomic orbitals of similar energy on the same atom to form equivalent hybrid orbitals with definite geometry. sp, sp2 and sp3 hybridizations explain linear, trigonal planar and tetrahedral arrangements respectively. Expanded geometries such as trigonal bipyramidal and octahedral are often described using sp3d and sp3d2 in the NCERT-level model. Hybridization also explains bond angles, equivalent bonds and the relation between s-character and bond strength.

Molecular orbital theory describes bonding by combining atomic orbitals to form molecular orbitals spread over the entire molecule. When atomic orbitals combine constructively, a lower-energy bonding molecular orbital forms; when they combine destructively, a higher-energy antibonding molecular orbital forms. Electrons fill molecular orbitals according to Aufbau principle, Pauli exclusion principle and Hund’s rule. Bond order is calculated as half the difference between bonding and antibonding electrons. A positive bond order indicates stability, while zero bond order means the molecule is unstable. MOT successfully explains bond order, relative bond length, bond enthalpy and magnetic behavior. Its most famous NEET application is explaining why O2 is paramagnetic, which Lewis theory and simple VBT fail to explain.

Hydrogen bonding is a strong dipole-dipole interaction that occurs when hydrogen is bonded to a highly electronegative and small atom such as fluorine, oxygen or nitrogen, and is attracted to a lone pair on another electronegative atom. It may be intermolecular, as in water and HF, or intramolecular, as in o-nitrophenol. Hydrogen bonding explains high boiling points of H2O, HF and NH3 compared with similar hydrides, the open structure of ice, solubility of alcohols and biological structures such as proteins and DNA. Metallic bonding is explained by metal cations immersed in a sea of delocalized electrons. This model explains electrical conductivity, thermal conductivity, malleability, ductility and metallic lustre.