NEET 2016 · Chemistry

NEET 2016 Chemistry Questions with Solutions

The NEET 2016 paper had 43 Chemistry questions from 22 chapters.

Chemical Bonding and Molecular Structure had the most questions (7), followed by Hydrocarbons with 4.

10 questions below have the answer and explanation free; the other 33 are in Premium.

Chemistry questions
43
Chapters covered
22
Solved free here
10 of 43
Easy / Medium / Hard
10 / 25 / 8

Difficulty is NEET MIND's own tag for each question.

Chapter-wise: NEET 2016 Chemistry

How many questions each chapter had in NEET 2016. Open a chapter for its questions from every year.

  1. Chemical Bonding and Molecular Structure7 Qs
  2. Hydrocarbons4 Qs
  3. Coordination Compounds3 Qs
  4. Electrochemistry3 Qs
  5. Solutions3 Qs
  6. Amines2 Qs
  7. Equilibrium2 Qs
  8. Haloalkanes and Haloarenes2 Qs
  9. Organic Chemistry: Some Basic Principles and Techniques2 Qs
  10. S-Block Elements2 Qs
  11. Thermodynamics2 Qs
  12. Alcohols, Phenols and Ethers1 Q
  13. Aldehydes, Ketones and Carboxylic Acids1 Q
  14. Chemical Kinetics1 Q
  15. General Principles And Processes Of Isolation Of Elements1 Q
  16. Hydrogen1 Q
  17. Polymers1 Q
  18. Redox Reactions1 Q
  19. Solid State1 Q
  20. Some Basic Concepts of Chemistry1 Q
  21. Structure of Atom1 Q
  22. The d- and f-Block Elements1 Q

All 43 NEET 2016 Chemistry questions

In paper order. Try each one, then open the answer where it is shown.

  1. Question 1 (NEET 2016, Q46)

    Alcohols, Phenols and EthersEasy
    Which one of the following compounds shows the presence of intramolecular hydrogen bond?
    1. Option A: H₂O₂
    2. Option B: HCN
    3. Option C: Cellulose
    4. Option D: Concentrated acetic acid

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  2. Question 2 (NEET 2016, Q47)

    ElectrochemistryMedium
    The molar conductivity of a 0.5 mol dm−30.5\ \text{mol dm}^{-3} solution of AgNO₃ with electrolytic conductivity of 5.76×10−3 S cm−15.76 \times 10^{-3}\ \text{S cm}^{-1} at 298 K298\ \text{K} is:
    1. Option A: 2.88 S cm² mol⁻¹
    2. Option B: 11.52 S cm² mol⁻¹
    3. Option C: 0.086 S cm² mol⁻¹
    4. Option D: 28.8 S cm² mol⁻¹

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  3. Question 3 (NEET 2016, Q48)

    Chemical KineticsMedium
    The decomposition of phosphine (PH3)(PH_3) on tungsten at low pressure is a first-order reaction. It is because:
    1. Option A: Rate is proportional to the surface coverage
    2. Option B: Rate is inversely proportional to the surface coverage
    3. Option C: Rate is independent of the surface coverage
    4. Option D: Rate of decomposition is very slow

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  4. Question 4 (NEET 2016, Q49)

    SolutionsMedium
    The coagulation values in millimoles per litre of the electrolytes used for the coagulation of As2S3As_2S_3 are given below: I. (NaCl)=52(NaCl)=52 II. (BaCl2)=0.69(BaCl_2)=0.69 III. (MgSO4)=0.22(MgSO_4)=0.22 The correct order of their coagulating power is:
    1. Option A: I > II > III
    2. Option B: II > I > III
    3. Option C: III > II > I
    4. Option D: III > I > II

    The answer and explanation for this question are in NEET MIND Premium.

  5. Question 5 (NEET 2016, Q50)

    ElectrochemistryMedium
    During the electrolysis of molten sodium chloride, the time required to produce 0.100.10 mol of chlorine gas using a current of 33 amperes is:
    1. Option A: 55 minutes
    2. Option B: 110 minutes
    3. Option C: 220 minutes
    4. Option D: 330 minutes

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  6. Question 6 (NEET 2016, Q51)

    Structure of AtomEasy
    How many electrons can fit in the orbital for which n=3n = 3 and l=1l = 1?
    1. Option A: 2
    2. Option B: 6
    3. Option C: 10
    4. Option D: 14
    Show answer & explanation

    Correct answer: (A) 2

    Explanation

    For n=3n = 3 and l=1l = 1, the orbital belongs to the 3p3p subshell. A single orbital can accommodate a maximum of two electrons with opposite spins. Hence option (A) is correct.

  7. Question 7 (NEET 2016, Q52)

    ThermodynamicsMedium
    For a sample of perfect gas when its pressure is changed isothermally from PiP_i to PfP_f, the entropy change is given by:
    1. Option A: ΔS=nRln⁡(PfPi)\Delta S = nR\ln\left(\dfrac{P_f}{P_i}\right)
    2. Option B: ΔS=nRln⁡(PiPf)\Delta S = nR\ln\left(\dfrac{P_i}{P_f}\right)
    3. Option C: ΔS=nRTln⁡(PfPi)\Delta S = nRT\ln\left(\dfrac{P_f}{P_i}\right)
    4. Option D: ΔS=RTln⁡(PiPf)\Delta S = RT\ln\left(\dfrac{P_i}{P_f}\right)

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  8. Question 8 (NEET 2016, Q53)

    SolutionsEasy
    The van't Hoff factor (i)(i) for a dilute aqueous solution of the strong electrolyte barium hydroxide is:
    1. Option A: 0
    2. Option B: 1
    3. Option C: 2
    4. Option D: 3

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  9. Question 9 (NEET 2016, Q54)

    EquilibriumHard
    The percentage of pyridine (C5H5N)(C_5H_5N) that forms pyridinium ion (C5H5N+H)(C_5H_5N^+H) in a 0.10 M0.10\ \text{M} aqueous pyridine solution (Kb for C5H5N=1.7×10−9)(K_b\text{ for }C_5H_5N = 1.7 \times 10^{-9}) is:
    1. Option A: 0.0060%
    2. Option B: 0.013%
    3. Option C: 0.77%
    4. Option D: 1.6%

    The answer and explanation for this question are in NEET MIND Premium.

  10. Question 10 (NEET 2016, Q55)

    Solid StateMedium
    In calcium fluoride, having the fluorite structure, the coordination numbers for calcium ion (Ca2+)(Ca^{2+}) and fluoride ion (F−)(F^-) are:
    1. Option A: 4 and 2
    2. Option B: 6 and 6
    3. Option C: 8 and 4
    4. Option D: 4 and 8
    Show answer & explanation

    Correct answer: (C) 8 and 4

    Explanation

    In fluorite structure of CaF2CaF_2: - Ca2+Ca^{2+} ions form FCC arrangement. - F−F^- ions occupy all tetrahedral voids. Thus: - Coordination number of Ca2+Ca^{2+} is 88. - Coordination number of F−F^- is 44. Hence option (C) is correct.

  11. Question 11 (NEET 2016, Q56)

    ThermodynamicsMedium
    If the Ecell∘E^\circ_{cell} for a given reaction has a negative value, which of the following gives the correct relationships for the values of ΔG∘\Delta G^\circ and KeqK_{eq}?
    1. Option A: ΔG∘>0; Keq<1\Delta G^\circ > 0;\ K_{eq} < 1
    2. Option B: ΔG∘>0; Keq>1\Delta G^\circ > 0;\ K_{eq} > 1
    3. Option C: ΔG∘<0; Keq>1\Delta G^\circ < 0;\ K_{eq} > 1
    4. Option D: ΔG∘<0; Keq<1\Delta G^\circ < 0;\ K_{eq} < 1

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  12. Question 12 (NEET 2016, Q57)

    SolutionsEasy
    Which one of the following is incorrect for ideal solution?
    1. Option A: ΔHmix=0\Delta H_{mix} = 0
    2. Option B: ΔUmix=0\Delta U_{mix} = 0
    3. Option C: ΔP=Pobs−Pcalculated by Raoult′s law=0\Delta P = P_{obs} - P_{calculated\ by\ Raoult's\ law} = 0
    4. Option D: ΔGmix=0\Delta G_{mix} = 0

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  13. Question 13 (NEET 2016, Q58)

    EquilibriumMedium
    The solubility of AgCl(s)AgCl(s) with solubility product 1.6×10−101.6 \times 10^{-10} in 0.1 M NaCl0.1\ \text{M}\ NaCl solution would be:
    1. Option A: 1.26×10−5 M1.26 \times 10^{-5}\ \text{M}
    2. Option B: 1.6×10−9 M1.6 \times 10^{-9}\ \text{M}
    3. Option C: 1.6×10−11 M1.6 \times 10^{-11}\ \text{M}
    4. Option D: Zero

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  14. Question 14 (NEET 2016, Q59)

    Some Basic Concepts of ChemistryHard
    Suppose the elements XX and YY combine to form two compounds XY2XY_2 and X3Y2X_3Y_2. When 0.10.1 mole of XY2XY_2 weighs 10 g10\ \text{g} and 0.050.05 mole of X3Y2X_3Y_2 weighs 9 g9\ \text{g}, the atomic weights of XX and YY are:
    1. Option A: 40, 30
    2. Option B: 60, 40
    3. Option C: 20, 30
    4. Option D: 30, 20

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  15. Question 15 (NEET 2016, Q60)

    ElectrochemistryEasy
    The number of electrons delivered at the cathode during electrolysis by a current of 11 ampere in 6060 seconds is (charge on electron =1.60×10−19 C=1.60\times10^{-19}\ \text{C}):
    1. Option A: 6×10236\times10^{23}
    2. Option B: 6×10206\times10^{20}
    3. Option C: 3.75×10203.75\times10^{20}
    4. Option D: 7.48×10237.48\times10^{23}

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  16. Question 16 (NEET 2016, Q61)

    HydrogenMedium
    Boric acid is an acid because its molecule:
    1. Option A: Contains replaceable H+H^+ ion
    2. Option B: Gives up a proton
    3. Option C: Accepts OH⁻ from water releasing proton
    4. Option D: Combines with proton from water molecule
    Show answer & explanation

    Correct answer: (C) Accepts OH⁻ from water releasing proton

    Explanation

    Boric acid acts as a Lewis acid. It accepts OH−OH^- ions from water: B(OH)3+H2O→[B(OH)4]−+H+B(OH)_3 + H_2O \rightarrow [B(OH)_4]^- + H^+ Thus it releases proton indirectly. Hence option (C) is correct.

  17. Question 17 (NEET 2016, Q62)

    Coordination CompoundsMedium
    AlF₃ is soluble in HF only in presence of KF. It is due to the formation of:
    1. Option A: K3[AlF3H3]K_3[AlF_3H_3]
    2. Option B: K3[AlF6]K_3[AlF_6]
    3. Option C: AlH3AlH_3
    4. Option D: K[AlF3H]K[AlF_3H]

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  18. Question 18 (NEET 2016, Q63)

    General Principles And Processes Of Isolation Of ElementsEasy
    Zinc can be coated on iron to produce galvanized iron but the reverse is not possible. It is because:
    1. Option A: Zinc is lighter than iron
    2. Option B: Zinc has lower melting point than iron
    3. Option C: Zinc has lower negative electrode potential than iron
    4. Option D: Zinc has higher negative electrode potential than iron
    Show answer & explanation

    Correct answer: (D) Zinc has higher negative electrode potential than iron

    Explanation

    Standard reduction potentials: EZn2+/Zn∘=−0.76 VE^\circ_{Zn^{2+}/Zn} = -0.76\ \text{V} EFe2+/Fe∘=−0.44 VE^\circ_{Fe^{2+}/Fe} = -0.44\ \text{V} Zinc has more negative electrode potential and oxidizes more easily. Thus zinc protects iron sacrificially. Hence option (D) is correct.

  19. Question 19 (NEET 2016, Q64)

    S-Block ElementsEasy
    The suspension of slaked lime in water is known as:
    1. Option A: Limewater
    2. Option B: Quicklime
    3. Option C: Milk of lime
    4. Option D: Aqueous solution of slaked lime
    Show answer & explanation

    Correct answer: (C) Milk of lime

    Explanation

    A suspension of slaked lime Ca(OH)2Ca(OH)_2 in water is called milk of lime. Hence option (C) is correct.

  20. Question 20 (NEET 2016, Q65)

    Chemical Bonding and Molecular StructureMedium
    The hybridizations of atomic orbitals of nitrogen in NO2+NO_2^+, NO3−NO_3^- and NH4+NH_4^+ respectively are:
    1. Option A: sp, sp3 and sp2sp,\ sp^3\ \text{and}\ sp^2
    2. Option B: sp2, sp3 and spsp^2,\ sp^3\ \text{and}\ sp
    3. Option C: sp, sp2 and sp3sp,\ sp^2\ \text{and}\ sp^3
    4. Option D: sp2, sp and sp3sp^2,\ sp\ \text{and}\ sp^3

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  21. Question 21 (NEET 2016, Q66)

    Chemical Bonding and Molecular StructureEasy
    Which one of the following fluoro-compounds is most likely to behave as a Lewis base?
    1. Option A: BF3BF_3
    2. Option B: PF3PF_3
    3. Option C: CF4CF_4
    4. Option D: SiF4SiF_4

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  22. Question 22 (NEET 2016, Q67)

    Chemical Bonding and Molecular StructureHard
    Which of the following pairs of ions is isoelectronic and isostructural?
    1. Option A: CO32−, NO3−CO_3^{2-},\ NO_3^-
    2. Option B: ClO3−, CO32−ClO_3^-,\ CO_3^{2-}
    3. Option C: SO32−, NO3−SO_3^{2-},\ NO_3^-
    4. Option D: ClO3−, SO32−ClO_3^-,\ SO_3^{2-}

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  23. Question 23 (NEET 2016, Q68)

    S-Block ElementsMedium
    In context with beryllium, which one of the following statements is incorrect?
    1. Option A: It is rendered passive by nitric acid
    2. Option B: It forms Be2CBe_2C
    3. Option C: Its salts rarely hydrolyze
    4. Option D: Its hydride is electron-deficient and polymeric
    Show answer & explanation

    Correct answer: (C) Its salts rarely hydrolyze

    Explanation

    Beryllium salts hydrolyze readily because of the small size and high polarizing power of Be2+Be^{2+} ion. Therefore the statement 'Its salts rarely hydrolyze' is incorrect. Hence option (C) is correct.

  24. Question 24 (NEET 2016, Q69)

    Redox ReactionsMedium
    Hot concentrated sulphuric acid is a moderately strong oxidizing agent. Which of the following reactions does not show oxidizing behaviour?
    1. Option A: Cu+2H2SO4→CuSO4+SO2+2H2OCu + 2H_2SO_4 \rightarrow CuSO_4 + SO_2 + 2H_2O
    2. Option B: 3S+2H2SO4→3SO2+2H2O3S + 2H_2SO_4 \rightarrow 3SO_2 + 2H_2O
    3. Option C: C+2H2SO4→CO2+2SO2+2H2OC + 2H_2SO_4 \rightarrow CO_2 + 2SO_2 + 2H_2O
    4. Option D: CaF2+H2SO4→CaSO4+2HFCaF_2 + H_2SO_4 \rightarrow CaSO_4 + 2HF
    Show answer & explanation

    Correct answer: (D) CaF2+H2SO4→CaSO4+2HFCaF_2 + H_2SO_4 \rightarrow CaSO_4 + 2HF

    Explanation

    In the reaction: CaF2+H2SO4→CaSO4+2HFCaF_2 + H_2SO_4 \rightarrow CaSO_4 + 2HF there is no change in oxidation state of any element. Thus concentrated sulphuric acid does not act as an oxidizing agent in this reaction. Hence option (D) is correct.

  25. Question 25 (NEET 2016, Q70)

    Chemical Bonding and Molecular StructureMedium
    Which of the following pairs of d-orbitals will have electron density along the axes?
    1. Option A: dz2, dxzd_{z^2},\ d_{xz}
    2. Option B: dxz, dyzd_{xz},\ d_{yz}
    3. Option C: dz2, dx2−y2d_{z^2},\ d_{x^2-y^2}
    4. Option D: dxy, dx2−y2d_{xy},\ d_{x^2-y^2}

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  26. Question 26 (NEET 2016, Q71)

    Chemical Bonding and Molecular StructureEasy
    The correct geometry and hybridization for XeF4XeF_4 are:
    1. Option A: Octahedral, sp3d2sp^3d^2
    2. Option B: Trigonal bipyramidal, sp3dsp^3d
    3. Option C: Planar triangular, sp3d3sp^3d^3
    4. Option D: Square planar, sp3d2sp^3d^2

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  27. Question 27 (NEET 2016, Q72)

    Chemical Bonding and Molecular StructureMedium
    Among the following, which one is a wrong statement?
    1. Option A: PH5PH_5 and BiCl5BiCl_5 do not exist
    2. Option B: pπ−dπp\pi-d\pi bonds are present in SO2SO_2
    3. Option C: SeF4SeF_4 and CH4CH_4 have same shape
    4. Option D: I3+I_3^+ has bent geometry

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  28. Question 28 (NEET 2016, Q73)

    Coordination CompoundsHard
    The correct increasing order of trans-effect of the following species is:
    1. Option A: NH₃ > CN⁻ > Br⁻ > C₆H₅⁻
    2. Option B: CN⁻ > C₆H₅⁻ > Br⁻ > NH₃
    3. Option C: Br⁻ > CN⁻ > NH₃ > C₆H₅⁻
    4. Option D: CN⁻ > Br⁻ > C₆H₅⁻ > NH₃

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  29. Question 29 (NEET 2016, Q74)

    The d- and f-Block ElementsMedium
    Which one of the following statements related to lanthanoids is incorrect?
    1. Option A: Europium shows +2 oxidation state
    2. Option B: The basicity decreases as the ionic radius decreases from Pr to Lu
    3. Option C: All the lanthanoids are much more reactive than aluminium
    4. Option D: Ce(+4)solutions are widely used as oxidizing agent in volumetric analysis

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  30. Question 30 (NEET 2016, Q75)

    Coordination CompoundsHard
    Jahn-Teller effect is not observed in high spin complexes of:
    1. Option A: d7d^7
    2. Option B: d8d^8
    3. Option C: d4d^4
    4. Option D: d9d^9

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  31. Question 31 (NEET 2016, Q76)

    Haloalkanes and HaloarenesMedium
    Which of the following can be used as the halide component for Friedel-Crafts reaction?
    1. Option A: Chlorobenzene
    2. Option B: Bromobenzene
    3. Option C: Chloroethene
    4. Option D: Isopropyl chloride
    Show answer & explanation

    Correct answer: (D) Isopropyl chloride

    Explanation

    Friedel-Crafts alkylation requires formation of a stable carbocation. Isopropyl chloride forms relatively stable secondary carbocation. Aryl and vinyl halides do not undergo Friedel-Crafts reactions easily. Hence option (D) is correct.

  32. Question 32 (NEET 2016, Q77)

    Chemical Bonding and Molecular StructureMedium
    In which of the following molecules, all atoms are coplanar?
    1. Option A: Option 1
    2. Option B: Option 2
    3. Option C: Option 3
    4. Option D: Option 4

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  33. Question 33 (NEET 2016, Q78)

    PolymersMedium
    Which one of the following structures represents nylon 6,6 polymer?
    1. Option A: Option 1
    2. Option B: Option 2
    3. Option C: Option 3
    4. Option D: Option 4
    Show answer & explanation

    Correct answer: (D) Option 4

    Explanation

    Nylon-6,6 is formed by condensation polymerization of adipic acid and hexamethylene diamine. Its repeating unit is: [−NH−(CH2)6−NH−CO−(CH2)4−CO−]n[-NH-(CH_2)_6-NH-CO-(CH_2)_4-CO-]_n Hence option (D) is correct.

  34. Question 34 (NEET 2016, Q79)

    Organic Chemistry: Some Basic Principles and TechniquesMedium
    In pyrrole, the electron density is maximum on:
    1. Option A: 2 and 3
    2. Option B: 3 and 4
    3. Option C: 2 and 4
    4. Option D: 2 and 5

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  35. Question 35 (NEET 2016, Q80)

    HydrocarbonsMedium
    Which of the following compounds shall not produce propene by reaction with HBr followed by elimination reaction?
    1. Option A: Option 1
    2. Option B: Option 2
    3. Option C: Option 3
    4. Option D: Option 4

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  36. Question 36 (NEET 2016, Q81)

    AminesHard
    Which one of the following nitro-compounds does not react with nitrous acid?
    1. Option A: Option 1
    2. Option B: Option 2
    3. Option C: Option 3
    4. Option D: Option 4

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  37. Question 37 (NEET 2016, Q84)

    HydrocarbonsHard
    In the given reaction, the product PP is:
    1. Option A: Option 1
    2. Option B: Option 2
    3. Option C: Option 3
    4. Option D: Option 4

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  38. Question 38 (NEET 2016, Q85)

    AminesMedium
    A given nitrogen-containing aromatic compound A reacts with Sn/HClSn/HCl, followed by HNO2HNO_2 to give an unstable compound B, on treatment with phenol, forms a beautiful coloured compound C with the molecular formula C12H10N2OC_{12}H_{10}N_2O. The structure of compound A is:
    1. Option A: Option 1
    2. Option B: Option 2
    3. Option C: Option 3
    4. Option D: Option 4

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  39. Question 39 (NEET 2016, Q86)

    Haloalkanes and HaloarenesMedium
    Consider the reaction: CH3CH2CH2Br+NaCN→CH3CH2CH2CN+NaBrCH_3CH_2CH_2Br + NaCN \rightarrow CH_3CH_2CH_2CN + NaBr This reaction will be the fastest in:
    1. Option A: Ethanol
    2. Option B: Methanol
    3. Option C: N,N-dimethylformamide (DMF)
    4. Option D: Water
    Show answer & explanation

    Correct answer: (C) N,N-dimethylformamide (DMF)

    Explanation

    The reaction proceeds through an SN2S_N2 mechanism. SN2S_N2 reactions are fastest in polar aprotic solvents because such solvents do not strongly solvate nucleophiles. DMF is a polar aprotic solvent and therefore enhances the nucleophilicity of CN−CN^- ion. Hence option (C) is correct.

  40. Question 40 (NEET 2016, Q87)

    HydrocarbonsMedium
    The correct structure of the product A formed in the reaction is:
    1. Option A: Option 1
    2. Option B: Option 2
    3. Option C: Option 3
    4. Option D: Option 4

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  41. Question 41 (NEET 2016, Q88)

    Organic Chemistry: Some Basic Principles and TechniquesHard
    Which among the given molecules can exhibit tautomerism?
    1. Option A: III only
    2. Option B: Both I and III
    3. Option C: Both I and II
    4. Option D: Both II and III

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  42. Question 42 (NEET 2016, Q89)

    Aldehydes, Ketones and Carboxylic AcidsMedium
    The correct order of strengths of the carboxylic acids shown below is:
    1. Option A: I > II > III
    2. Option B: II > III > I
    3. Option C: III > II > I
    4. Option D: II > I > III

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  43. Question 43 (NEET 2016, Q90)

    HydrocarbonsEasy
    The compound that will react most readily with gaseous bromine has the formula:
    1. Option A: C3H6C_3H_6
    2. Option B: C2H2C_2H_2
    3. Option C: C4H10C_4H_{10}
    4. Option D: C2H4C_2H_4

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